The drift velocity of electrons in a conductor is given by,
\(v_d=\frac I{neA}\)
Where,
I = current in the conductor,
e = electric charge and
n = electron concentration
A = area of cross-section of the wire.
For a copper and an iron wire; ni < nc. i.e., the free electron density of copper is greater than the free electron density of iron. So, the drift velocity of electrons for iron is greater than copper wire.