In fluorescent lamp . the inner wall of the glass tube is coated with fluorescent powder. There are two electrodes at its two ends, The tube of fluorescent lamp is filled with mercury vapor.
When the powder is switched on, the cathode is heated and it emits electrons. When electrons move through mercury vapor towards anode it collides with the Hg atoms. During the collision, the ultra violet rays are produced. The UV rays strike the fluorescent powder in the inner wall to produce visible light.
Fluorescent lamps work by ionizing mercury vapor in a glass tube. This causes electrons in the gas to emit photons at UV frequencies. The UV light is converted into standard visible light using a phosphor coating on the inside of the tube.When you turn on a fluorescent light bulb (correctly called a "lamp"), there is a very brief jump in current when the ballast charges the cathodes and causes the lamp to start. This inrush of current can be many times greater than the normal operating current of the lamp.
Principles of operation
The fundamental mechanism for conversion of electrical energy to light is emission of a photon when an electron in a mercury atom falls from an excited state into a lower energy level. Electrons flowing in the arc collide with the mercury atoms. If the incident electron has enough kinetic energy, it transfers energy to the atom's outer electron, causing that electron to temporarily jump up to a higher energy level that is not stable. The atom will emit an ultraviolet photon as the atom's electron reverts to a lower, more stable, energy level. Most of the photons that are released from the mercury atoms have wavelengths in the ultraviolet (UV) region of the spectrum, predominantly at wavelengths of 253.7 and 185 nanometers (nm). These are not visible to the human eye, so ultraviolet energy is converted to visible light by the fluorescence of the inner phosphor coating. The difference in energy between the absorbed ultra-violet photon and the emitted visible light photon goes toward heating up the phosphor coating.
Electric current flows through the tube in a low-pressure arc discharge. Electrons collide with and ionize noble gas atoms inside the bulb surrounding the filament to form a plasma by the process of impact ionization. As a result of avalanche ionization, the conductivity of the ionized gas rapidly rises, allowing higher currents to flow through the lamp.
The fill gas helps determine the electrical characteristics of the lamp, but does not give off light itself. The fill gas effectively increases the distance that electrons travel through the tube, which allows an electron a greater chance of interacting with a mercury atom. Additionally, argon atoms, excited to a metastable state by impact of an electron, can impart energy to a mercury atom and ionize it, described as the Penning effect. This lowers the breakdown and operating voltage of the lamp, compared to other possible fill gases such as krypton.